Effect of Monosaccharides and Disaccharides Type on Ionic Conductivity of Liquid Electrolyte Based Lithium Iodide
DOI:
https://doi.org/10.25077/jif.13.2.70-79.2021Abstract
Liquid electrolyte was prepared by dissolving glucose, fructose, sucrose and lactose separately with different percentage of lithium iodide (10 – 35%) in aqueous solution of 1% acetic acid. Liquid electrolyte is characterized using conductivity meter to determine ionic conductivity. Computer simulations of Density Functional Theory (DFT) was used to identify the dominant functional groups on monomers such as glucose, sucrose, fructose and lactose when interact with the lithium salt by using B3LYP/6-31G ++ (d, p) basis set. The highest ionic conductivity for monosaccharide is glucose at 28.20 mS/cm while for disaccharide is lactose at 28.00 mS/cm with percentage of salt at 35 wt.%. Ionic conductivity increases when concentration of salt increase because there is an interaction between salt with functional groups of compounds. Based on computer simulations of DFT, interaction between lithium with compounds can be occurred due to negative electrostatic potential on the molecule. Electronegativity value of oxygen atom in glucose (-0.562e) and lactose (-0.567e) higher than fructose (-0.559e) and sucrose (-0.515e). Functional groups that are dominant to interact when interact with lithium salt are O-15 for glucose and O-17 for lactose due to the shorter bond length, the stronger energy attraction between functional groups with lithium.
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Ahmad, A., Rahman, M. Y. A., Low, S. P., & Hamzah, H. (2011). Effect of LiBF4 salt concentration on the properties of plasticized MG49-TiO2 based nanocomposite polymer electrolyte. International Scholarly Research Notices.
Aziz, S. B., & Abidin, Z. H. Z. (2013). Electrical conduction mechanism in solid polymer electrolytes: new concepts to arrhenius equation. Journal of Soft Matter, 2013, 1-8.
Benhamou, K., Kaddami, H., Magnin, A., Dufresne, A., & Ahmad, A. (2015). Bio-based polyurethane reinforced with cellulose nanofibers: a comprehensive investigation on the effect of interface. Carbohydrate Polymers, 122, 202-211.
Gil, D. M., Lestard, M. D., Estévez-Hernández, O., Duque, J., & Reguera, E. (2015). Quantum chemical studies on molecular structure, spectroscopic (IR, Raman, UV–Vis), NBO and Homo–Lumo analysis of 1-benzyl-3-(2-furoyl) thiourea. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 145, 553-562.
Govindarajan, M., Karabacak, M., Udayakumar, V. & Periandy, S. (2012). FTIR, FTRaman and UV Spectral Investigation: Computed Frequency Estimation Analysis and Electronic Structure Calculations on Chlorobenzene Using HF and DFT. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 88, 37-48.
Imperiyka, M., Ahmad, A., Hanifah, S. A., & Rahman, M. Y. A. (2014). Preparation and characterization of polymer electrolyte of glycidyl methacrylate-methyl methacrylate-LiClO4 plasticized with EC. International Journal of Polymer Science, 2014-1, 371-377.
Joshi, B. D., & Chaudhary, P. N. (2013). Molecular structure, MESP, homo-lumo and vibrational analysis of β-asarone using density functional theory. Kathmandu Univ J Sci Eng Tech, 9, 1-14.
Khanmirzaei, M. H., & Ramesh, S. (2013). Ionic transport and FTIR properties of lithium iodide doped biodegradable rice starch-based polymer electrolytes. Int J Electrochem Sci, 8(7), 9977-9991.
Liu, K., Lin, Y., Miller, J. D., Liu, J. & Wang, X. (2017). Study of Sucrose Based Room Temperature Solid Polymer Electrolyte for Lithium Sulfur Battery. Journal of The Electrochemical Society, 164 (2), 447-452.
Luque, F. J., López, J. M. & Orozco, M. (2000). Perspective on Electrostatic Interactions of a Solute with a Continuum. A Direct Utilization of Ab Initio Molecular Potentials for the Prevision of Solvent Effects. Theoretical Chemistry Accounts, 103 (3-4), 343-345.
Mobarak, N. N., Ramli, N., Ahmad, A. & Rahman, M. Y. A. (2012). Chemical Interaction and Conductivity of Carboxymethyl Κ-Carrageenan Based Green Polymer Electrolyte. Solid State Ionics, 224, 51-57.
Scrocco, E. & Tomasi, J. (1978). Electronic Molecular Structure, Reactivity and Intermolecular Forces: An Euristic Interpretation by Means of Electrostatic Molecular Potentials. Advances in Quantum Chemistry, 11, 115-193.
Selvin, P. C., Perumal, P., Selvasekarapandian, S., Monisha, S., Boopathi, G., & Chandra, M. L. (2018). Study of proton-conducting polymer electrolyte based on K-carrageenan and NH4SCN for electrochemical devices. Ionics, 24(11), 3535-3542.
Zulkefli, F. N., Navaratnam, S., & Ahmad, A. H. (2015). Proton conducting biopolymer electrolytes based on starch incorporated with ammonium thiocyanate. Advanced Materials Research, 1112, 275-278.
Wade, L. G. (2014). Organic chemistry. International Editions, 1174-1178, Pearson, London.
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