Sintesis Lapisan TiO2 Pada Substrat ITO Menggunakan Metode Elektrodeposisi dan Spin Coating

Authors

  • Anggia Arista Jurusan Fisika FMIPA, Universitas Andalas, Indonesia
  • Dahyunir Dahlan Jurusan Fisika FMIPA, Universitas Andalas, Indonesia
  • Syukri Syukri Jurusan Kimia FMIPA, Universitas Andalas, Indonesia

DOI:

https://doi.org/10.25077/jif.8.1.17-27.2016

Abstract

Telah dilakukan sintesis lapisan tipis TiO2 menggunakan metode elektrodeposisi dan spin coating. Elektrodeposisi menggunakan larutan elektrolit 0,25 M TiCl3. Dalam penelitian ini juga dilakukan variasi larutan elektrolit dengan penambahan CTAB, PEG dan penambahan H3BO3. Selanjutnya lapisan TiO2 disintesis menggunakan metode spin coating yang dilakukan di atas lapisan TiO2 setelah elektrodeposisi. Larutan prekusor yang digunakan adalah Titanium Butoxide (Ti(OC4H9)4 dengan waktu aging larutan 48 jam. Hasil karakterisasi SEM menunjukkan elektrodeposisi lapisan tipis TiO2 dengan penambahan CTAB dan PEG menghasilkan morfologi permukaan yang homogen dan berpori pada lapisan TiO2. Berdasarkan hasil karakterisasi UV-Vis, energi gap TiO2 pada sampel yang disintesis menggunakan metode elektrodeposisi adalah  3,86 eV, sedangkan nilai energi gap yang didapat pada sampel menggunakan metode spin coating adalah 3,18 eV.

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References

Atmono,T., Yunanto, 2001, Pembuatan dan Karakterisasi Multilayer SiO2/TiO2, Prosiding Pertemuan dan Presentasi Ilmiah Penelitian Dasar Ilmu Pengetahuan dan Teknologi Nuklir P3TM-BATAN, Yogyakarta.

Ceotto, E.F., Souza,B., Teschke, 2000, Ionic Surfactant Films Imaed by Atomic Force Microscopy, Departamento de Fisica, Universidade Federal de Vicosa, 36571-000 Vicosa, MG, Brazil.

Grätzel, M., 2003, Review Dye-Sensitized Solar Cells, Journal of Photochemistry and Photobiology C: Photochemistry Reviews, Volume 4, hal 145-153. DOI: https://doi.org/10.1016/S1389-5567(03)00026-1

Hikam, M., 2002, Studi Kekristalan PbZrx Til-xO3 yang Disiapkan Dengan Pelapisan Putar (Spin Coating), Jurnal Sains Materi Indonesia, ISSN 1411-1098.

Jitputti, J. Pavasupree S., Suzuki Y., dan Yoshikawa S., 2008, Synthesis of TiO2 Nanotube and Its Photocatalytic Activity For H2 Evolution, Japanese Journal of Applied Physics, Volume 47, Number 1, hal 751-756. DOI: https://doi.org/10.1143/JJAP.47.751

Karuppuchamy, S., Andou, Y.,dan Endo, T., 2012, Synthesis of Nanostuctured TiO2 Photoelectrode for Flexible Dye Sensitized Solar Cell Application, Apply Nanosci, DOI 10.1007/s13204-012-0140-6. DOI: https://doi.org/10.1007/s13204-012-0140-6

Kong F.T., Dai S.Y., dan Wang K.J., 2007, Review of Recent Progress in Dye-Sensitized Solar Cell, Hindawi Publishing Corporation Advances in Optoelectronics, Article ID 75384. DOI: https://doi.org/10.1155/2007/75384

Nadeak, S.M.R. dan Susanti, D., 2012, Variasi Temperatur dan Waktu Tahan Kalsinasi Terhadap Unjuk Kerja Semikonduktor TiO2 sebagai Dye Sensitized solar cell (DSSC) dengan Dye dari Ekstrak Buah Naga Merah, Jurnal Teknik ITS, Vol. 1, ISSN 2301-9271.

Nugroho, A., dan Noviarti, 2011, Analisis Radionuklida 235 U Dalam Pelat Elemen Bakar (Peb) U3si2-Al Densitas 2,96 G/Cm3 Pasca Iradiasi, ISSN 0216-3128.

Nurmawarti, I., Abdullah, M., 2009, Distribusi Celah Pita Energi Titania Kotor, Jurnal Nanosains dan Nanoteknologi, ISSN 1979-0880, hal 38-42.

Perdana, Ramadhani., 2014, Pengaruh Suhu Pemanasan dan Waktu Aging Terhadap Sifat Fisis TiO2 yang Disintering Menggunakan Metode Sol Gel Spin Coating, Tesis, FMIP UNAND, Padang. DOI: https://doi.org/10.25077/jif.6.1.18-24.2014

Putama, I.L.M., 2014, Sintesis Lapisan Tipis TiO2 Dengan Metode Elektrodeposisi Menggunakan Variasi Arus Kontinu dan Arus Pulsa, Tesis, FMIPA UNAND, Padang.

Sotter, E., X. Vilanova, E. Liobet, M. Stankova. Correig., 2005, Niobium Doped Titanium Nano powder for gas sensor Applications, Journal of Optoelectronics and Advanced Material Vol. 7. No. 3. PP. 1395-1398.

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Published

2016-03-01

How to Cite

Arista, A., Dahlan, D., & Syukri, S. (2016). Sintesis Lapisan TiO2 Pada Substrat ITO Menggunakan Metode Elektrodeposisi dan Spin Coating. JURNAL ILMU FISIKA | UNIVERSITAS ANDALAS, 8(1), 17–27. https://doi.org/10.25077/jif.8.1.17-27.2016

Issue

Vol. 8 No. 1 (2016): March 2016

Section

Riset Artikel

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