Effects of Surfactants on the Stability of Nickel Ferrite/Water Nanofluid

Authors

  • Riyadi Adnan Mahmudi Magnetic and Photonic Research Group, Physics Department, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jl. Ganesha No. 10, Bandung 40132, Indonesia
  • Akhmad Yusuf Magnetic and Photonic Research Group, Physics Department, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jl. Ganesha No. 10, Bandung 40132, Indonesia
  • Inge Magdalena Sutjahja Magnetic and Photonic Research Group, Physics Department, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jl. Ganesha No. 10, Bandung 40132, Indonesia

DOI:

https://doi.org/10.25077/jif.17.1.31-40.2025

Keywords:

NiFe2O4 nanofluid, Surfactant, Nanofluid stability, Zeta potential, Thermal conductivity

Abstract

Nanofluid stability is a critical factor for the effective application of nanofluids in various fields. One simple and effective method to enhance nanofluid stability is through the addition of surfactants. This study examines the effect of different surfactants on the stability of nickel ferrite (NiFe₂O₄)/water nanofluid. The nanofluids were synthesis using the two-step method, and the surfactants investigated inculded oleic acid, polyethylene glycol 400, tetrabutylammonium bromide, gum arabic, and citric acid. Different concentrations for each surfactant were tested by adjusting the nanoparticles-to-surfactant ratio. The suspension stability was evaluated through visual observation, Zeta potential measurements, and thermal conductivity analysis. The most stable NiFe₂O₄/water nanofluid was achieved using citric acid surfactant, with a nanoparticles-to-surfactant volume ratio of 1:0.25, a Zeta potential value of -35.0 mV and an average thermal conductivity of 0.585 ± 0.007 W/m·K. The results of this study are important for developing nanofluid and magnetic nanofluid systems with optimum conductive heat transfer performance.

Downloads

Download data is not yet available.

References

Ahmadi, M. H., Mirlohi, A., Nazari, M. A., & Ghasempour, R. (2018). A Review of Thermal Conductivity of Various Nanofluids. Journal of Molecular Liquids, 265, 181-188. DOI: https://doi.org/10.1016/j.molliq.2018.05.124

Alva, G., Lin, Y., & Fang, G. (2018). An overview of thermal energy storage systems. Energy, 144, 341–378. https://doi.org/10.1016/j.energy.2017.12.037. DOI: https://doi.org/10.1016/j.energy.2017.12.037

Amiri, M., Salavati-Niasari, M., & Akbari, A. (2019). Magnetic nanocarriers: Evolution of spinel ferrites for medical aplications. Advances in Colloid and Interface Science, 265, 29-44. DOI: https://doi.org/10.1016/j.cis.2019.01.003

Ataei, M., Moghanlou, F. S., Noorzadeh, S., Vajdi, M., & Asl, M. S. (2020). Heat transfer and flow characteristics of hybrid Al2O3/TiO2–water. Heat and Mass Transfer, 56, 2757–2767. DOI: https://doi.org/10.1007/s00231-020-02896-9

Chakraborty, S., & Panigrahi, P. K. (2020). Stability of nanofluid: A review. Applied Thermal Engineering, 174. DOI: https://doi.org/10.1016/j.applthermaleng.2020.115259

Doganay, S., Alsangur, R., & Turgut, A. (2019). Effect of external magnetic field on thermal conductivity and viscosity of magnetic nanofluids: A review. Materials Research Express, 6(11). https://doi.org/10.1088/2053-1591/ab44e9 DOI: https://doi.org/10.1088/2053-1591/ab44e9

Guo, Z. (2020). A review on heat transfer enhancement with nanofluids. Journal of Enhanced Heat Transfer, 27(1), 1–70. https://doi.org/10.1615/JEnhHeatTransf.2019031575. DOI: https://doi.org/10.1615/JEnhHeatTransf.2019031575

Healy, J. J., de Groot, J. J., & Kestin, J. (1976). The theory of the transient hot-wire method for measuring thermal conductivity. Physica B+C, 82(2), 392–408. https://doi.org/10.1016/0378-4363(76)90203-5 DOI: https://doi.org/10.1016/0378-4363(76)90203-5

Huminic, G., & Huminic, A. (2016). Heat transfer and flow characteristics of conventional fluids in curved tubes: A revie. Renewable and Sustainable Energy Reviews, 58, 1327–1347. DOI: https://doi.org/10.1016/j.rser.2015.12.230

Ibna, A. A., & Bodius, S. (2020). A review on nanofluid: preparation, stability, thermophysical properties, heat transfer characteristic and aplication. Springer Nature Aplied Sciences, 2, 1636.https://doi.org/10.1007/s42452-020-03427-1 DOI: https://doi.org/10.1007/s42452-020-03427-1

Jung, S. Y., & Park, H. (2021). Experimental investigation of heat transfer of Al2O3 nanofluid in a. International Journal of Heat and Mass Transfer, 179. DOI: https://doi.org/10.1016/j.ijheatmasstransfer.2021.121729

Karimi, A., Goharkhah, M., Ashjaee, M., & Shafii, M. B. (2015). Thermal Conductivity of Fe2O3 and Fe3O4 Magnetic Nanofluids Under the Influence of Magnetic Field. International Journal of Thermophysics, 36(10–11), 2720–2739. https://doi.org/10.1007/s10765-015-1977-1 DOI: https://doi.org/10.1007/s10765-015-1977-1

Karimi, A., Sadatlu, M. A., Saberi, B., Shariatmadar, H., & Ashjaee, M. (2015). Experimental investigation on thermal conductivity of water based nickel ferrite nanofluids. Advanced Powder Technology, 25(6), 1529-1536. https://doi.org/10.1016/j.apt.2015.08.015 DOI: https://doi.org/10.1016/j.apt.2015.08.015

Katiyar, A., Dhar, P., Nandi, T., & Das, S. K. (2016). Magnetic field induced augmented thermal conduction phenomenon in magneto-nanocolloids. Journal of Magnetism and Magnetic Materials, 419, 588–599. https://doi.org/10.1016/j.jmmm.2016.06.065 DOI: https://doi.org/10.1016/j.jmmm.2016.06.065

Kumar, A., & Subudhi, S. (2018). Preparation, characteristics, convection and applications of magnetic nanofluids: A review. Heat and Mass Transfer/Waerme- Und Stoffuebertragung, 54(2), 241–265. https://doi.org/10.1007/s00231-017-2114-4. DOI: https://doi.org/10.1007/s00231-017-2114-4

Mehta, B., Subhedar, D., Panchal, H., & Said, Z. (2022). Synthesis, stability, thermophysical properties and heat transfer applications of nanofluid – A review. Journal of Molecular Liquids, 364, 120034. https://doi.org/10.1016/j.molliq.2022.120034. DOI: https://doi.org/10.1016/j.molliq.2022.120034

MTI Corporation. (2023). Nano, 3D & Chemical A-Z. MTI Online Store. https://www.mtixtl.com/index.aspx

Okonkwo, E. C., Wole-Osho, I., Almanassra, I. W., Abdullatif, Y. M., & Al-Ansari, T. (2021). An updated review of nanofluids in various heat transfer devices. In Journal of Thermal Analysis and Calorimetry (Vol. 145, Issue 6). Springer International Publishing. https://doi.org/10.1007/s10973-020-09760-2. DOI: https://doi.org/10.1007/s10973-020-09760-2

Pubchem . (2024). Citric Acid. Pubchem-National Center for Biotechnology Information-National Library of Medicine. https://pubchem.ncbi.nlm.nih.gov/compound/Citric-Acid

PubChem. (2024). Arabic Gum. Pubchem-National Center for Biotechnology Information-National Library of Medicine. https://pubchem.ncbi.nlm.nih.gov/compound/Arabic-gum

PubChem. (2024). Oleic Acid. Pubchem-National Center for Biotechnology Information-National Library of Medicine. https://pubchem.ncbi.nlm.nih.gov/compound/Oleic-Acid

PubChem. (2024). Polyethylene Glycol 400. Pubchem-National Center for Biotechnology Information-National Library of Medicine. https://pubchem.ncbi.nlm.nih.gov/compound/Polyethylene-Glycol-400

PubChem. (2024). Tetrabutylammonium bromide. Pubchem-National Center for Biotechnology Information National Library of Medicine. https://pubchem.ncbi.nlm.nih.gov/compound/Tetrabutylammonium-bromide

Selim, M. M., El-Safty, S., Tounsi, A., & Shenashen, M. (2023). Review of the impact of the external magnetic field on the chracteristics of magnetic nanofluids. Alexandria Engineering Journal, 76, 75-89. DOI: https://doi.org/10.1016/j.aej.2023.06.018

Wang, J., Li, G., Li, T., Zeng, M., & Sundén, B. (2021). Effect of various surfactants on stability and thermophysical properties of nanofluids. Journal of Thermal Analysis and Calorimetry, 143, 4057–4070. DOI: https://doi.org/10.1007/s10973-020-09381-9

Wang, J., Yang, X., Klemeš, J. J., Tian, K., Ma, T., & Sunden, B. (2023). A review on nanofluid stability: preparation and application. Renewable and Sustainable Energy Reviews, 188(November 2022). https://doi.org/10.1016/j.rser.2023.113854 DOI: https://doi.org/10.1016/j.rser.2023.113854

Wuhu Nuowei Chemistry. (2023). Tetrabutylammonium bromide. Wuhu Nuowei chemistry Co., Ltd. https://en.nuowei-chem.com

Yadav, P., Gupta, S. M., & Sharma, S. K. (2022). A review on stabilization of carbon nanotube nanofluid. Journal of Thermal Analysis and Calorimetry, 147, 6537–6561. DOI: https://doi.org/10.1007/s10973-021-10999-6

Yılmaz, A. D., Emrullah, A., & Metin, G. (2023). The effects of particle mass fraction and static magnetic field on the thermal performance of NiFe2O4 nanofluid in a heat pipe. International Journal of Thermal Sciences, 183, 107875. DOI: https://doi.org/10.1016/j.ijthermalsci.2022.107875

Younes, H., Mao, M., Sohel Murshed, S. M., Lou, D., Hong, H., & Peterson, G. P. (2022). Nanofluids: Key parameters to enhance thermal conductivity and its applications. Applied Thermal Engineering, 207, 118202. https://doi.org/10.1016/j.applthermaleng.2022.118202 DOI: https://doi.org/10.1016/j.applthermaleng.2022.118202

Zhang, T., Zoua, Q., Cheng, Z., Chena, Z., Liua, Y., & Jiang, Z. (2020). Effect of particle concentration on the stability of water-based SiO2 nanofluid. Powder Technology, 379, 457-465. DOI: https://doi.org/10.1016/j.powtec.2020.10.073

Zheng, N., Wang, L., & Sun, Z. (2021). The effects of ultrasonication power and time on the dispersion stability of few-layer graphene nanofluids under the constant ultrasonic energy consumption condition. Ultrasonics Sonochemistry, 80, 105816. DOI: https://doi.org/10.1016/j.ultsonch.2021.105816

Downloads

Published

2025-02-01

How to Cite

Mahmudi, R. A., Yusuf, A. ., & Sutjahja, I. M. . (2025). Effects of Surfactants on the Stability of Nickel Ferrite/Water Nanofluid. JURNAL ILMU FISIKA | UNIVERSITAS ANDALAS, 17(1), 31–40. https://doi.org/10.25077/jif.17.1.31-40.2025

Issue

Section

Research Article

Citation Check